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  Olivier Roubeau

Olivier Roubeau Cientifico Titular (Tenured researcher CSIC)
Ph. D. in Chemistry (2002), Leiden University, The Netherlands

Departamento de Física de la Materia Condensada and
Instituto de Ciencia de Materiales de Aragón.

Facultad de Ciencias
Universidad de Zaragoza
C/ Pedro Cerbuna 12,
E-50009 Zaragoza, SPAIN
Tel: +34-976762461
Fax: +34-976761229
E-mail: roubeau@unizar.es

more about molchip research at molchip or at molchip


Resarch interests / selection of recent relevant publications
(Reprint downloads are only for personal use)

Spin crossover and charge transfer coordination compounds

"Enhancement of spin-crossover cooperativity mediated by lone pair−pi interactions and halogen bonding"
N. Nassirinia, S. Amani, S. J. Teat, O. Roubeau, P. Gamez, Chem. Commun. 2014, 50, 1003-1005 link

"High-temperature photo-induced switching and pressure-induced transition in a cooperative molecular spin-crossover material"
G. A. Craig, J. Sánchez Costa, O. Roubeau, S. J. Teat, H. J. Shepherd, M. Lopes, G. Molnár, A. Bousseksou, G. Aromí, Dalton Trans. 2014, 43, 729-737 link
"Multimetastability in a Spin-Crossover compound leading to different High-Spin-to-Low-Spin relaxation dynamics"
G. A. Craig, J. Sánchez Costa, S. J. Teat, O. Roubeau, D. S. Yufit, J. A. K. Howard, G. Aromí, Inorg. Chem. 2013, 52, 7203-7209 link

"Influence of supramolecular bonding contacts on the spin crossover behaviour of iron(II) complexes from 2,2´-dipyridylamino/s-triazine ligands"
N. Wannarit, O. Roubeau, S. Youngme, S. J. Teat, P. Gamez, Dalton Trans. 2013, 42, 7120-7130 link


"Subtlety of the spin-crossover phenomenon observed with dipyridylamino-substituted triazine Ligands"
N. Wannarit, O. Roubeau, S. Youngme, P. Gamez, Eur. J. Inorg. Chem. 2013, 730-737 link

"Dinuclear complexes with a triple N1,N2-triazole bridge that exhibit partial spin crossover and weak antiferromagnetic interactions"
O. Roubeau, P. Gamez, S. J. Teat, Eur. J. Inorg. Chem. 2013, 934-942 link



"Triazole-based one-dimensional spin-crossover coordination polymers"
O. Roubeau, Chem. Eur. J. 2012, 18, 15230-15244 link

"A spin crossover ferrous complex with ordered magnetic ferric anions"
O. Roubeau, M. Evangelisti, E. Natividad, Chem. Commun. 2012, 7604-7606 link

Molecular magnetic compounds as cryogenic magnetocaloric materials

"Surface-confined molecular coolers for cryogenics"
G. Lorusso, M. Jenkins, G. González-Monge, A. Arauzo, J. Sesé, D. Ruiz-Molina, O. Roubeau, M. Evangelisti, Adv. Mater. 2013, 25, 2984-2988 link

"A dense Metal−Organic Framework for enhanced magnetic refrigeration"
G. Lorusso, J. W. Sharples, E. Palacios, O. Roubeau, E. K. Brechin, R. Sessoli, A. Rossin, F. Tuna, E. J. L. McInnes, D. Collison, M. Evangelisti, Adv. Mater. 2013, 25, 4653-4656 link


"Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks"
G. Lorusso, M. A. Palacios, G. S. Nichol, E. K. Brechin, O. Roubeau, M. Evangelisti, Chem. Commun. 2012, 7592-7594 link

"Cryogenic magnetocaloric effect in a ferromagnetic molecular dimer"
M. Evangelisti, O. Roubeau, E. Palacios, A. Camón, T. N. Hooper, E. K. Brechin, J. J. Alonso, Angew. Chem. Int. Ed. 2011, 50, 6606-6609 link
Molecular compounds as spin-based quantum computing hardware



"Design of magnetic coordination complexes for quantum computing"
G. Aromí, D. Aguilà, P. Gamez, F. Luis, O. Roubeau, Chem. Soc. Rev. 2012, 41, 537-546 link
"Molecular prototypes for spin-based CNOT and SWAP quantum gates"
F. Luis, A. Repollés, M. J. Martínez-Pérez, D. Aguilà, O. Roubeau, D. Zueco, P. J. Alonso, M. Evangelisti, A. Camón, J. Sesé, L. A. Barrios, G. Aromí, Phys. Rev. Lett. 2011, 107, 117203 link

"Molecular assembly of two [Co(II)4] linear arrays"
D. Aguilà, L. A. Barrios, O. Roubeau, S. J. Teat, G. Aromí, Chem. Commun. 2011, 47, 707-709 link

"Synthesis and properties of a family of unsymmetric dinuclear complexes of Ln(III) (Ln = Eu, Gd or Tb)"
D. Aguilà, L. A. Barrios, F. Luis, A. Repollés, O. Roubeau, S. J. Teat, G. Aromí, Inorg. Chem. 2010, 49, 6784-6786 pdf

"Designed topology and site-selective metal composition in tetranuclear [MM⋅⋅⋅MM] (M=CoII, NiII, CuII) and [CuNi⋅⋅⋅NiCu] linear complexes"
L. A. Barrios, D. Aguilà, O. Roubeau, P. Gamez, J. Ribas-Ariño, S. J. Teat, G. Aromí, Chem. Eur. J. 2009, 15, 11235-11243 link

Extended coordination polymers of SMMs and other non-innocent building blocks

"Rational design of a photomagnetic chain: bridging Single-Molecule Magnets with a Spin-Crossover complex"
R. Ababei, C. Pichon, O. Roubeau, Y-G. Li, N. Bréfuel, L. Buisson, P. Guionneau, C. Mathonière, R. Clérac, J. Am. Chem. Soc. 2013, 135, 14840-14853 link
"Two-dimensional assembly of [MnIII2MnII2] Single-Molecule Magnets and [Cu(pic)2] linking units (Hpic = Picolinic acid)"
I-R. Jeon, R. Ababei, L. Lecren, Y-G. Li, W. Wernsdorfer, O. Roubeau, C. Mathonière, R. Clérac, Dalton Trans. 2010, 39, 4744-4746 link

"Bimetallic cyanido-bridged magnetic materials derived from manganese(III) Schiff-base complexes and pentacyanidonitrosylferrate(II) precursor"
R. Ababei, Y-G. Li, O. Roubeau, M. Kalisz, N. Bréfuel, C. Coulon, E. Harté, X. Liu, C. Mathonière, R. Clérac, New J. Chem. 2009, 33, 1237-1248 link


"Rational assembly of high-spin polynuclear magnetic complexes into coordination networks: the case of a [Mn4] Single-Molecule Magnet building block"
O. Roubeau, R. Clérac, Eur. J. Inorg. Chem. 2008, 28, 4325-4342 (Microreview) pdf
Carbon nanotubes covalent functionalization
"Dissolution and alkylation of industrially produced multi-walled carbon nanotubes"
D. Voiry, C. Vallés, O. Roubeau, A. Pénicaud, Carbon 2011, 49, 170-175 pdf

"Stoechiometric control of single walled carbon nanotubes functionalization"
D. Voiry, O. Roubeau, A. Pénicaud, J. Mater. Chem. 2010, 20, 4385-4391 pdf
"Influence of surface functionalization on the thermal and electrical properties of nanotube−PVA composites"
C. Bartholome, P. Miaudet, A. Derré, M. Maugey, O. Roubeau, C. Zakri, P. Poulin, Comp. Sci. Technol. 2008, 68, 2568-2573 pdf



Active collaborations

Fernando Luis, Marco Evangelisti, MolChip, ICMA, Universidad de Zaragoza and CSIC

Miguel Castro, Eva Natividad, Ramón Burriel, Propiedades Térmicas de Materiales, ICMA, Universidad de Zaragoza and CSIC

Guillem Aromí, Universitat Barcelona (GMMF)

Nuria Aliaga-Alcalde, ICREA and Universitat Barcelona (GMMF)

Patrick Gamez, ICREA and Universitat Barcelona

Rodolphe Clérac, M3 team, CRPP-CNRS, France

Sylvestre Bonnet, MCBIM, Leiden University, The Netherlands



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©2014 Departamento de Física de la Materia Condensada (Fac. de Ciencias) |Teléfono Dpto. 976 761230, Fax 976 761229
©2014 Universidad de Zaragoza (Pedro Cerbuna 12, 50009 ZARAGOZA-ESPAÑA | Tfno. información: (34) 976-761000)
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